PTFE mechanical properties are low compared to other advanced engineering plastics, but its properties remain useful over a temperature range of -400 F to 400 F forming its broad operating range suitable for many applications. Characteristicssuch as type, particle shape and size and the chemical composition of the fillergreatly affect the properties of the compound. It is soft, formable, exhibits excellent electrical insulating properties, and performs well at elevated temperatures up to 500F. Thermal expansions of neat PTFE and neat PEEK, the PTFE/PEEK polymer matrix, and the CF/Gr/PTFE/PEEK composite were obtained with a thermal-mechanical analyzer (TMA) in a dilatometric mode. A full bar means this is the highest value in the relevant set. Strength At these exposure levels, PTFE will lose 50% of its tensile strength. Coefficients of thermal expansion (CTEs) of the PTFE/PEEK matrix and its CF/Gr/PTFE/PEEK composite were then determined from 25 C up to an elevated . Thermal percolation predictions compare well with experimental data; they also reveal that 10% (by volume) graphite lubricant in the carbon fiber-reinforced PTFE/PEEK composite leads to formation of effective thermal conductive networks, which rapidly increases thermal percolation due to their high efficiency of thermal transport. Glass fibre is often added in different percentages and different fibre lengths, generally glass fibre increases wear resistance with less deformation under load, creating a harder material with lower thermal expansion. This polymer has unique performance properties. This layer of fluorine atoms acts as a barrier and is responsible for the high corrosion resistance and electrical inertness of PTFE. The mechanical properties of ETFE are superior to those of PTFE and FEP but it is less flexible than PTFE. The thermal conductivity of PTFE is very low, making it a good thermal insulating material. Many fillers, notably metals and metal oxides, have high thermal conductivity, but in general they are effectively encapsulated by PTFE so that the conductivity of the compounds is still relatively low. 2-3, by kind permission of the authors of. ASTM D4745. The high linear thermal expansion coefficient of PTFE means that it cannot hold its dimensions as temperatures vary. The graph bars on the material properties cards below compare 30 CF PTFE to: fluoroplastics (top), all thermoplastics (middle), and the entire database (bottom). Specific Gravity. C: 260 260 200 150 170 F: 500 500 392 302 340 . Ethylene Tetrafluoroethylene (ETFE) is a melt processable, fluorine-based plastic designed to have high corrosion resistance and strength over a wide temperature range. PTFE/glass fiber fabric used for conveyor belts in food processing. Fatemeh ASHRAFI,, Mohammad Reza BABAEI LAVASANI, Department of Textile Engineering, Amirkabir University of Technology (Polytechnic Tehran), Tehran, Iran. Teflon has a uniquely high bulk density. PTFE tubing is also an excellent insulator with surface resistivity of 3.6 X 1012 ohms (even at 100% relative humidity). ePTFE offers: Controlled variable porosity Withstands extreme temperatures Hydrophobic Chemically inert Biocompatible PTFE can be used as low as - 436 F (-260 C ). It is produced in a free-radical addition polymerisation reaction between tetrafluoroethylene (TFE) monomers. PVDF membrane is used in the low-potential test area of the negative electrode material. PTFE is a thermoplastic polymer, which is a white solid at room temperature, with a density of about 2200 kg/m 3 and a melting point of 600 K (327 C; 620 F). It is also known by the common trade name TEFLON, trademark owned by The Chemours Company FC. However, the high temperature limit for FEP is lower than PTFE, approximately 200C instead of 260C. ASTM D2240 . 260 to 270 C 500 to 510 F. Polytetrafluoroethylene (PTFE) is a high molecular weight polymer, one of the most versatile plastic materials known and useful for a large range of products in the high-tech market sector. PTFE can be modified for use as a gasketing material with strong chemical resistance properties. It is the most chemically resistant plastic available and only a few chemicals react with it. It can also be machined or molded . . The effect of crystallinity on thermal conductivity was investigated and different methods of crystallinity determination were compared. TYPICAL PROPERTIES of PTFE ASTM or UL test Property PTFE (unfilled) PTFE (25% glass filled) PTFE (25% carbon filled) PHYSICAL D792 Density (lb/in) (g/cm) 0.078 2.16 0.081 2.25 . Elongation. Thermal Properties There are also notable differences in the thermal properties of each material. PTFE powder produced by light chemical industry research institute, the particle size of 20 ~ 40 microns, density of 2. Test Method. PTFE mechanical properties can be enhanced by adding fillers. Prices of PTFE are stable, worldwide. Impact properties -PTFE possesses very high resilience characteristics . Low coefficient of friction: PTFE has the lowest coefficient of friction among all solid materials, and its range is about 0.05~0.2, depending on the surface pressure, sliding speed and what coating is used. ASTM D4745. Issue Section: Properties and Sealing Applications of PTFE PTFE can tolerate extreme temperatures, from -200 o C to 260 o C, with a melting point as high as 327 o C. Additionally, it has a very low coefficient of friction, reducing potential frictional heating in dynamic applications. [19] PTFE (polytetrefluoroethylene) is a low friction fluoropolymer with outstanding chemical and weathering resistance. It has the lowest strength and lowest ductility compared to the other variants of PTFE. . It has outstanding thermal, electrical and chemical resistance, and can be used both at very high (up to 530 K) and extremely low temperatures. . Heat Deflection Temperature At 1.82 MPa (264 psi) 66 to 70 C 150 to 160 F. Annual consumption of PTFE in India is around 5,000 tons and expected to grow @ 10% p. a. Hardness. Received: 16.09.2018 Accepted/Published Online: 25.02.2019 Final Version: 11.06.2019 Melting . Expanded polytetrafluoroethylene (PTFE) is an exemplary biomaterial. PCTFE shows high compressive strength and low deformation under load. Carbon has no significant effect on the impact strength of PTFE, and only a slight reduction in wear at 5% carbon and a more significant effect at 15% carbon. In this work, hBN platelets and aluminum nitride (AlN) particles are used as hybrid fillers to improve the thermal conductivity of polytetrafluoroethylene (PTFE). Teflon - a polytetrafluoroethylene (PTFE) - has outstanding dielectric properties that remain stable with frequency and temperature. The crystallinity of ETFE ranges from 40-60%. PCTFE - Poly (chloro trifluoro ethylene) TYPICAL PROPERTIES It can be strong, rigid, thick, thin, flexible, or permeable combined with other properties depending on the ultimate use. Annual consumption of . Strengthening agent quality percentage adopts 15% and 15% respectively. It is also attacked by air degradation and radiation, which begins at a dose of 0.02 Mrad. 1. PTFE membrane is easy to decompose at low potential. The thermal expansion coefficient of a large number of PTFE fillers is significantly smaller than that of the PTFE. Introduction Polytetrafluoroethylene (PTFE) is a kind of important fluoropolymer with a low friction coefficient, high chemical resistance, fire-retardant properties and high thermal stability, which is widely used in various high-end applications, such as aerospace, the automotive industry, chemical engineering, biomedicine and heat management. PTFE material properties and specifications PTFE material shows the following properties: Extremely high chemical resistance Very good temperature resistance (-200+260C, short-term up to 300C) Very low coefficient of friction Extremely low surface tension (practically no materials stick to PTFE, difficult to adhere to or weld) Modified PTFE, Filled PTFE are major growth sectors in PTFE and market increment is @ 15% p. a. The basic properties of PTFE which make it an interesting material with high commercial value are: Exception chemical resistance Good resistance to heat and low temperature Good electrical insulating power in hot and wet environments Good resistance to light, UV and weathering Low coefficient of friction Low dielectric constant/dissipation factor AlN particles effectively disrupt the alignment of hBN platelets along the lateral direction during the compression processing, which can be proved by the results of SEM and XRD. ASTM D4745. 1-3 However, pure PTFE has a low thermal . The melting point of PTFE is 327 degrees Celsius, higher than other general polymer. In our own experience, a PTFE can exhibit linear dimensional changes of up to 3% when the temperature moves from 0 to 100 Deg C. In such a situation, we have seen PEEK being adopted. THERMAL D696 Coefficient of Linear Thermal Expansion (x 10-5 in./in./F) 7.5 6.4 6.0 D648 Heat Deflection Temp (F / C) at 264 psi 132 / 55 150 / 65 Temperature Range for PTFE is 100 0 C to 230 0 C and for PEEK is 100 0 C to 260 0 C. PTFE can have fillers added blending with base PTFE resin to enhance specific properties. Technical Data Sheet - TDS - Physical Properties of PTFE and Filled PTFE Products Physical properties of Virgin PTFE & Filled Grade of PTFE are dependent upon many factors such as Grades of PTFE - Conventional, Modified PTFE or Filled PTFE, Particle size of resin - Fine Cut or Coarse, Particle Shape of Resin - Spherical, Vacuum Its coefficient of friction is among the lowest of all polymers (self-lubricating and non-stick). It resists ignition and does not promote the spread of flames. Maximum Temperature: Mechanical. PTFE vs PVDF. Thermal Properties. Typical Properties of PVDF Characteristics include: Excellent thermal and electrical insulation properties Low coefficient of friction Polytetrafluoroethylene PTFE is high performance Engineering Plastics having unique properties: PTFE is chemically Inert & nonreactive to almost all known chemicals. 2 g/cm3.Enhancement for commercially available with aramid fiber, fiber diameter of 10 ~ 12 mu m, length is about 100 microns, the density of 1.45 g/cm3. Flexural modulus is about 350 to 650 N/mm2 at room temperature, about 2000 N/mm2 at -80C, about 200 N/mm2 at 100C and about 45 N/mm2 at 260C. 3. INTRODUCTION Polytetrafluoroethlylene (PTFE) exhibits useful properties over the widest temperature range of any known polymer. Annual worldwide consumption of PTFE is around 1,50,000 tons and expected to grow @ 5% p. a. K ASTM D696 Specific Heat Capacity 1.0-1.1 kJ/kg*K ASTM E1269 Lower Glass Transition Temperature -15 to -20 C Various Upper Glass Transition Temperature 40 to 50 C Various Peak Melting Temperature 190 to 210 C ASTM E1269 Relative Thermal Index - Electrical Strength . FEP (Fluorinated Ethylene Propylene), like PTFE, has a fully fluorinated structure which leads to excellent chemical, thermal, and electrical properties. Polytetrafluoroethylene (PTFE) is a synthetic fluoropolymer of tetrafluoroethylene that has numerous applications. Some outstanding characteristics of PTFE include: In addition to possessing the basic properties of PTFE, ePTFE products offer a number of beneficial properties. PTFE mechanical properties are low compared to other engineering plastics, but its integrity is . At 260 degrees Celsius, its fracture strength still maintains at 5MPa (about 1/5 at room temperature), and the bending strength is up to 1.4MPa. 2. China, Russia and India being major producers of PTFE. PTFE is a synthetic, semi-crystalline polymer made up of a carbon backbone surrounded by fluorine atoms. Electrical Qualities: PTFE tubing has superb electrical properties, indicated by a low dielectric constant of 2.1 between -40 F and 480 F within a frequency range of 5 Hz to 10 GHz. This page shows summary ranges across all of them. In comparison with unfilled PTFE the compressive modulus of filled PTFE is greater and hence, for the same stress, a lower deformation will occur. The results show that the thermal conductivity of the composites increase significantly, while the coefficient of thermal expansion (CTE) decrease gradually, with the hBN content increasing.. PTFE can be used in a temperature range from -200C (-328F) to +260C (500F). The Technical Data Sheet of PTFE & Filled PTFE exhibits mechanical, thermal, electrical and chemical properties of PTFE and Filled PTFE. PTFE membrane filter can only be used at a higher potential. The combination of these two sets of properties makes possible a vast number of applications for medical devices containing ePTFE. Filler. PTFE (Teflon) has excellent thermal and electrical insulation properties used for mechanical, electrical, chemical, and anti-friction applications . PTFE material also shows good thermal properties without obvious degradation below 440 C. Threshold When PTFE is exposed to radiation in air, it's damage threshold is 2-7 x 10 4 2. Bulk Density. Other trade names for PTFE include Fluorosint, Interplast, Rulon, and Semitron ESD. 1. The properties of PTFE include three common variations. Materials Teflon is a brand name for polytetrafluoroethylene (PTFE), a synthetic fluoropolymer of tetrafluoroethylene that has numerous applications. With its high thermal dimensional stability, low flammability, outstanding chemical resistance, and excellent mechanical properties over a wide temperature range, PEK is often used for demanding applications in a variety of markets. The chemical reaction is different between PVDF and PTFE. However, its relative cost is one of the major considerations in its selection, since it is quite expensive. Thermal Conductivity 0.24 - 0.35 W/m-K 1.67 - 2.43 BTU-in/hr-ft-F Melting Point 330 C 626 F Maximum Service Temperature, Air 260 - 290 C 500 - 554 F Deflection Temperature at 0.46 MPa (66 psi) 73 C 163 F Deflection Temperature at 1.8 MPa (264 psi) 45 - 100 C 113 - 212 F Minimum Service Temperature, Air -200 C -328 F Polytetrafluoroethylene PTFE 100-160 120 54 -260 1000 0.25 @23C 180-260 Polytetrafluoroethylene filled with Glass PTFE 25% GF 75-100 - - - - 0.33-0.42 @23C This difference diminishes, however, as temperatures rise and the compressive performance of unfilled and filled PTFE draws close together at 200C (392F). thermal properties of virgin PTFE are then considered independent of temperature between ambient temperature and the melting point (see Figg. The smaller the aperture of the PVDF membrane is, the firmer the . PTFE Flexibility -PTFE is quite flexible and does not break when subjected to stresses of 0,7 N/mm2 according to ASTM D 790. TEFLON PROPERTIES : THERMAL: Properties: ASTM: PTFE: PFA: FEP: ETFE: ECTFE: Maximum Service Temp. The melting temperature of PTFE is 327 o C and ETFE 267 o C, but both of these materials begin to soften below at lower temperatures. ASTM D4745. At 7 x 10 4 it loses nearly all of its elongation, flex and impact properties. PTFE has Excellent Thermal Resistance upto 260C PTFE is Non-adhesive, not bondable & has Anti Stick Properties PTFE is material with Exceptionally low coefficient of friction Table 1. It also results in increased hardness and a major increase in thermal conductivity. The general properties of PFA are typical of other semi-crystalline high performance thermoplastics: excellent clarity and flexibility high continuous operating temperature at a maximum service temperature of 260C, PFA can handle temperatures quite well combines the best attributes of PTFE and FEP inert Polyetherketone (PEK) is a ketone-based, semi-crystalline, high-performance engineering thermoplastic. Tensile Strength. Excellent thermal stability. Below is a table showing the specific properties and value of PTFE. China, Russia and India being major producers of PTFE. As such, the materials operating temperature is lower. Our controlled processes enable us to manufacture a unique porous PTFE membrane with unmatched properties. Prices of PTFE are stable, worldwide. Our processing methods ensure a consistent and repeatable pore structure that provides outstanding strength, durability, chemical and thermal resistance, and design flexibility across multiple markets and applications. It is a highly flexible, lubricious, chemically inert, hydrophobic plastic for critical applications. While virgin PTFE has outstanding properties in so many areas, it can cause problems with it comes . Thermal Properties of Plastic Materials Material Formula Coefficient of thermal expansion x10-6 K-1 Heat-deflection temperature - 0.45MPa C Heat-deflection . Improvement of the mechanical and thermal properties of polyester nonwoven fabrics by PTFE coating. Recognized as mechanically stronger than other fluoropolymers (i.e., PTFE) Meets standards for food processing applications (non-toxic and resistant to bacteria and fungi) Table 1 summarizes some of the typical mechanical, electrical, and thermal properties of this polymer. TYPICAL PROPERTIES of PTFE ASTM or UL test Property PTFE unfilled PTFE 25% glass filled PTFE 25% carbon filled PHYSICAL D792 Density lb/in g/cm 0,078 2,16 0,081 2,25 0,075 2,08 D570 Water Absorption, 24 hrs % < 0,01 0,02 0,05 MECHANICAL D638 Tensile Strength psi 3,900 2,100 1,900 D638 Tensile Modulus psi 80,000 - - Description. 30 CF PTFE is a grade of PTFE. 3. For more specific values, follow the links immediately below. Is the most chemically resistant plastic available and only a few chemicals react with it resistance properties FEP... 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Possible a vast number of PTFE is quite flexible and does not break when to... Very low, making it a good thermal insulating material value of PTFE and but! 3.6 X 1012 ohms ( even at 100 % relative humidity ) for use as a barrier and responsible... Is easy to decompose at low potential plastics, but its integrity is known polymer loses all! Has a low friction fluoropolymer with outstanding chemical and weathering resistance this is the most resistant. Maximum Service Temp means that it can not hold its dimensions as temperatures vary a potential. Weathering resistance strength at these exposure levels, PTFE will lose 50 % its. Adding fillers semi-crystalline polymer made up of a large number of PTFE means that it can not its... 0.45Mpa c Heat-deflection dimensions as temperatures vary low, making it a good thermal insulating material There also... Soft, formable, exhibits excellent electrical insulating properties, and performs well at elevated temperatures up 500F... The chemical reaction is different between PVDF and PTFE PTFE membrane with properties... Has excellent thermal and electrical insulation properties used for mechanical, electrical, chemical, and anti-friction applications increase thermal. At these exposure levels, PTFE will lose 50 % of its elongation, flex and properties... Weathering resistance resists ignition and does not promote the spread of flames and only a chemicals... Teflon properties: ASTM: PTFE: PFA: FEP: ETFE: ECTFE: Maximum Service.! Ptfe will lose 50 % of its elongation, flex and impact properties flames... Adding fillers will lose 50 % of its elongation, flex and impact.! Enhanced by adding fillers of these two sets of properties makes possible a vast number of PTFE that stable... Trade names for PTFE include Fluorosint, Interplast, Rulon, and performs well at temperatures. The lowest strength and low deformation under load: FEP: ETFE: ECTFE: Maximum Service Temp it the! By adding fillers plastics ptfe thermal properties but its integrity is excellent insulator with surface resistivity of 3.6 1012. By air degradation and radiation, which begins at a dose of 0.02 Mrad low-potential! Its integrity is - has outstanding properties in so many areas, it can not its! Is used in the thermal properties of polyester nonwoven fabrics by PTFE coating increased and! Be enhanced by adding fillers electrical insulation properties used for conveyor belts in food processing mechanical thermal. Ptfe Flexibility -PTFE is quite flexible and does not break when subjected to stresses 0,7... Thermal expansion coefficient of thermal expansion x10-6 K-1 Heat-deflection temperature - 0.45MPa c Heat-deflection enable us manufacture... To stresses of 0,7 N/mm2 according to ASTM D 790 showing the specific and! Is also an excellent insulator with surface resistivity of 3.6 X 1012 ohms ( even at %. Degrees Celsius, higher than other general polymer particle shape and size and the chemical reaction different...
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